Take a look at path selection policy configured for this LUN (seems like you're using the Fixed) and if your storage supports Round Robin policy, try change to Round Robin and you will see both paths with Active (I/O) status.
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Take a look at path selection policy configured for this LUN (seems like you're using the Fixed) and if your storage supports Round Robin policy, try change to Round Robin and you will see both paths with Active (I/O) status.